| 張永明 |
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張永明，男，1960年出生，1999年畢業(yè)于華東理工大學(xué)，獲材料科學(xué)與工程專業(yè)博士學(xué)位，同年進(jìn)入上海交通大學(xué)工作，現(xiàn)為上海交通大學(xué)教授，上海市領(lǐng)軍人才，全國勞動(dòng)模范，享受國務(wù)院政府特殊津貼專家，“泰山學(xué)者”特聘專家。從事含氟聚合物和含氟功能膜的研發(fā)。主持并圓滿完成國家863計(jì)劃、支撐計(jì)劃重大項(xiàng)目，實(shí)現(xiàn)了氯堿工業(yè)全氟離子膜的產(chǎn)業(yè)化，結(jié)束了中國沒有全氟離子膜的歷史，打破了制約我國氯堿工業(yè)安全運(yùn)行和健康發(fā)展的瓶頸，是中國氯堿工業(yè)發(fā)展的里程碑。同時(shí)開展的研究包括燃料電池新能源汽車核心材料、催化分離膜材料、海水淡化膜材料、儲能電池膜材料、特種潤滑材料等。所著《含氟功能材料》被評為化工領(lǐng)域科技圖書一等獎(jiǎng)。
主要研究方向
特種功能高分子材料
新能源汽車核心材料
催化分離膜材料、儲能電池膜材料
光電功能材料與生物材料
主持項(xiàng)目
歐盟第七框架項(xiàng)目
“十五”863計(jì)劃重大課題“全氟離子交換膜材料關(guān)鍵技術(shù)研究”
“十一五”國家支撐計(jì)劃重大項(xiàng)目“全氟離子膜工程技術(shù)研究”
“十一五”863計(jì)劃重點(diǎn)項(xiàng)目“新型制氫及高溫質(zhì)子交換膜燃料電池技術(shù)研發(fā)與應(yīng)用示范”
“十二五”國家支撐計(jì)劃重點(diǎn)項(xiàng)目“氯堿離子膜大規(guī)模應(yīng)用研究”
歐盟第六框架項(xiàng)目
中加合作項(xiàng)目“新型燃料電池質(zhì)子膜研究”
獲獎(jiǎng)情況
2007年山東省“泰山學(xué)者”
2009年山東省技術(shù)發(fā)明一等獎(jiǎng)（排名第一）
2010全國勞動(dòng)模范
2010年享受國務(wù)院特殊津貼專家
2010年所著《含氟功能材料》獲中國石化工業(yè)優(yōu)秀出版物獎(jiǎng)（圖書獎(jiǎng)）一等獎(jiǎng)（排名第一）
2010年“全氟離子交換膜工程技術(shù)研究”入選“十一五”國家重大科技成就
2011年“全氟離子膜工程技術(shù)研究團(tuán)隊(duì)”獲“十一五”國家科技計(jì)劃執(zhí)行優(yōu)秀團(tuán)隊(duì)獎(jiǎng)
2011年獲中國石化聯(lián)合會科技進(jìn)步二等獎(jiǎng)（排名第一）
2011年獲國家技術(shù)發(fā)明二等獎(jiǎng)（排名第一）
2012年獲“何梁何利科學(xué)與技術(shù)進(jìn)步獎(jiǎng)”
2012年獲“上海市領(lǐng)軍人才”稱號
2013年上海交通大學(xué)“凱原十佳教師”
主要學(xué)術(shù)兼職
國家分離膜標(biāo)準(zhǔn)化技術(shù)委員會委員
科技部國際合作評審專家
中國科技獎(jiǎng)勵(lì)評審專家
中國膜工業(yè)協(xié)會專家
中國氯堿協(xié)會專家
中國氟硅協(xié)會專家
中國無機(jī)鹽協(xié)會專家
中國儀表功能膜材料協(xié)會專家
《膜科學(xué)與技術(shù)》編委
《氯堿工業(yè)》編委
Publication List
2013
69 Yuan, W. Z.; Tan, Y.; Gong, Y.; Lu, P.; Lam, J. W. Y.; Shen, X. Y.; Feng, C.; Sung, H. H-Y.; Lu, Y.; Williams, I. D.; Sun, J. Z.; Zhang, Y.; Tang, B. Z. “Synergy between Twisted Conformation and Effective Intermolecular Interactions: Strategy for Efficient Mechanochromic Luminogens with High Contrast” Advanced Materials 2013, 26, 2837.
68 Gong, Y.; Tan, Y.; Liu, J.; Lu, P.; Feng, C.; Yuan, W. Z.; Lu, Y.; Sun, J. Z.; He, G.; Zhang, Y. “Twisted D–pi–A solid emitters: efficient emission and high contrast mechanochromism” Chemical Communications 2013, 49, 4009.
67 Zhu, Y.; Pei, S.; Tang, J.; Li, H.; Wang, L.; Yuan, W. Z.; Zhang, Y. “Enhanced chemical durability of perfluorosulfonic acid membranes through incorporation of terephthalic acid as radical scavenger” Journal of Membrane Science 2013, 432,
66 Yang, L.; Tang, J.; Li, L.; Ai, F.; Chen, X.; Yuan, W. Z.; Zhang, Y. “Properties of precursor solution cast PFSI membranes with various ion exchange capacities and annealing temperatures” RSC Advances 2013, 3, 7289.
65 Tang, J.; Yuan, W.; Zhang, Z.; Li, H.; Zhang, Y. “Evidence for a crystallite-rich skin on perfluorosulfonate ionomer membranes” RSC Advances 2013, 3, 8947.
64 Wang, C.; Li, H.; Zhao, J.; Zhu, Y.; Yuan, W. Z.; Zhang, Y. “Graphene Nanoribbons as A Novel Support Material for High Performance Fuel Cell Electrocatalysts” International Journal of Hydrogen Energy 2013, 38, 13230.
63 Yang, L.; Li, H.; Ai, F.; Chen, X.; Tang, J.; Zhu, Y.; Wang, C.; Yuan, W. Z.; Zhang, Y. “A New Method to Prepare High Performance Perfluorinated Sulfonicacid Ionomer/Porous Expanded Polytetrafluoroethylene Composite Membranes Based on Perfluorinated Sulfonyl Fluoride Polymer Solution” Journal of Power Sources 2013, 243, 392.
62 Gong, YY.; Tan, YQ.; Mei, J.; Zhang, YR.; Yuan, WZ.; Zhang, YM.; Sun, JZ.; Tang, B. Z. “Room temperature phosphorescence from natural products: Crystallization matters” Science China Chemistry 2013, 56, 1178.
61 Gong, YY.; Tan, YQ.; Li, H.; Zhang, YR.; Yuan, WZ.; Zhang, YM.; Sun, JZ.; Tang, B. Z. “Crystallization-induced phosphorescence of benzils at room temperature” Science China Chemistry 2013, 56, 1183.
60 Lu, YW.; Tan, YQ.; Gong, YY.; Li, H.; Yuan, WZ.; Zhang, YM.; Tang, B. Z. “High efficiency D-A structured luminogen with aggregation-induced emission and mechanochromic characteristics” Chinese Science Bulletin 2013, 58, 2719.
2012
59 Tang, J.; Yuan, W.; Wang, J.; Tang, J.; Li, H.; Zhang, Y. “Perfluorosulfonate ionomer membranes with improved through-plane proton conductivity fabricated under magnetic field” Journal of Membrane Science 2012, 423–424, 267.
58 Cai, Z.; Li, L.; Su, L.; Zhang, Y. “Supercritical carbon dioxide treated Nafion 212 commercial membranes for direct methanol fuel cells” Electrochemistry Communications 2012, 14, 9.
57 Cai, Z.; Liu, Y.; Zhao, J.; Li, L.; Zhang, Y.; Zhang, J. “Tris(trimethylsilyl) borate as electrolyte additive to improve performance of lithium-ion batteries” Journal of Power Sources 2012, 202, 341.
56 Yang, L.; Yuan, W.; Zhao, J.; Ai, F.; Chen, X.; Zhang, Y. “A Novel Approach to Prepare Uniaxially Aligned Nanofibers and Longitudinally Aligned Seamless Tubes Through Electrospinning” Macromolecular Materials and Engineering 2012, 297, 604.
55 Li, L.; Su, L.; Zhang, Y. “Enhanced performance of supercritical CO2 treated Nafion 212 membranes for direct methanol fuel cells” International Journal of Hydrogen Energy 2012, 37, 4439.
54 Cai, Z.; Liu, Y.; Liu, S.; Li, L.; Zhang, Y. “High performance of lithium-ion polymer battery based on non-aqueous lithiated perfluorinated sulfonic ion-exchange membranes” Energy & Environmental Science 2012, 5, 5690.
53 Chen, X.; Yuan, W. Z.; Zhao, J.; Yang, L.; Li, H.; Li, L.; Zhang, Y. “Thermal-mechanical stability of ethylene tetrafluoroethylene alternating copolymer, and modification thereof” Journal of Polymer Research 2012, 19, 9820.
52 Xu, A.; Yuan, W. Z.; Zhang, H.; Wang, L.; Li, H.; Zhang, Y. “Low-molecular-weight polytetrafluoroethylene bearing thermally stable perfluoroalkyl end-groups prepared in supercritical carbon dioxide” Polymer International 2012, 61 , 901.
51 Chen, X.; Yuan, W. Z.; Li, H.; Zhang, Y. “Rheological study on tetrafluoroethylene/hexafluoropropylene copolymer and its implication for processability” Journal of Applied Polymer Science 2012, 125, 3361.
50 Qin, S.; Li, H.; Yuan, W. Z.; Zhang, Y. “Fluorine-containing block copolymer particles with surface and internal hierarchical microphase separation structures” Soft Matter 2012, 8, 2471.
49 Qin, S.; Yuan, W. Z.; Li, H.; Zhang, Y. “Order–order phase transition and transformation in co-assembled particles from fluorinated FA/FB type diblock copolymers” Soft Matter 2012, 8, 8405.
48 Xu, A.; Li, H.; Yuan, W. Z.; Geng, B.; Zhang, S.; Zhang, H.; Wang, L.; Zhang, Y. “Radical homopolymerization of tetrafluoroethylene initiated by perfluorodiacyl peroxide in supercritical carbon dioxide: Reaction mechanism and initiation kinetics” European Polymer Journal 2012, 48,1431.
47 Yang, L.; Tang, J.; Li, L.; Chen, X.; Ai, F.; Yuan, W. Z.; Wang, L.; Zhang, Y. “High quality pristine perfluorosulfonated ionomer membranes prepared from perfluorinated sulfonyl fluoride solution” RSC Advances 2012, 2, 5950.
46 Chen, X.Y.; Yuan, W. Z.; Ai, F.; Li, H.; Li, L.; Wang, J.; Zhang, Y. “Melt rheological properties of ETFE: an attempt to illuminate the fluorine-substitution effect” Polymer Bulletin 2012, 69, 375.
45 Ai, F.; Wang, Q.; Yuan, W. Z.; Li, H.; Chen, X.; Yang, L.; Zhang, Y.; Pei, S. “Biocompatibility and anti-cracking performance of perfluorocarboxylic acid ionomer membranes for implantable biosensors” Journal of Materials Science 2012, 47, 5181.
44 Xu, A.; Yuan, W. Z.; Zhao, J.; Li, H.; Zhang, H.; Zhang, Y. “Copolymerizations of tetrafluoroethylene and perfluoropropylvinyl ether in supercritical carbon dioxide: Polymer synthesis, characterization, and thermal properties” Journal of Applied Polymer Science 2012, 124, 1785.
43 Zhu, H.; Tong, H.; Gong, Y.; Shao, S.; Deng, C.; Yuan, W. Z.; Zhang, Y. “Fluorene-and benzimidazole-based blue light-emitting copolymers: Synthesis, photophysical properties, and PLED applications” Journal of Polymer Science Part A: Polymer Chemistry 2012, 50 , 2172.
42 Qin, S.; Li, H.; Yuan, W. Z.; Zhang, Y. “Fabrication of polymeric honeycomb microporous films: breath figures strategy and stabilization of water droplets by fluorinated diblock copolymer micelles” Journal of Materials Science 2012, 47, 6862.
41 Ai, F.; Li, H.; Wang, Q.; Yuan, W. Z.; Chen, X.; Yang, L.; Zhao, J.; Zhang, Y. “Surface characteristics and blood compatibility of PVDF/PMMA membranes” Journal of Materials Science 2012, 47, 5030.
40 Chen, X. Y.; Zhang, Y. M. “Determining molecular weight scale and molecular weight distribution of ethylene-tetrafluoroethylene alternating copolymer via a rheological technique” Journal of Applied Polymer Science 2012, 125, 2442.
39 Yuan, W. Z.; Gong, Y.; Chen, S.; Shen, X. Y.; Lam, J. W.; Lu, P.; Lu, Y.; Wang, Z.; Hu, R.; Xie, N. “Efficient Solid Emitters with Aggregation-Induced Emission and Intramolecular Charge Transfer Characteristics: Molecular Design, Synthesis, Photophysical Behaviors, and OLED Application” Chemistry of Materials 2012, 24, 1518.
38 Yang, C.; Castelvetro, V.; Zhang, Y.; Hu, C. “Facile hydrophobic modification of hybrid poly (urethane-urea) methacrylate aqueous dispersions and films through blending with novel waterborne fluorinated acrylic copolymers” Colloid and Polymer Science 2012, 290, 491.
37 Ai, F.; Yuan, W. Z.; Wang, Q.; Li, H.; Zhang, Y.; Pei, S. “Enhancing the anti-cracking performance of perfluorosulfonic acid membranes for implantable biosensors through supercritical CO2 treatment” Journal of Materials Science 2012, 47, 3602.
2011
36 Zhao, J.; Xu, A.; Yuan, W. Z.; Gao, J.; Tang, J.; Wang, L.; Ai, F.; Zhang, Y. “Evaluation of electrospun nanofiber formation of perfluorosulfonic acid and poly (N-vinylpyrrolidone) through solution rheology” Journal of Materials Science 2011, 46, 7501.
35 Peron, J.; Edwards, D.; Haldane, M.; Luo, X.; Zhang, Y.; Holdcroft, S.; Shi, Z. “Fuel cell catalyst layers containing short-side-chain perfluorosulfonic acid ionomers” Journal of Power Sources 2011, 196, 179.
34 Yang, C.; Castelvetro, V.; Scalarone, D.; Bianchi, S.; Zhang, Y. “Three different β-cyclodextrins direct the emulsion copolymerization of a highly fluorinated methacrylate toward distinctive nanostructured particle morphologies’’ Journal of Polymer Science Part A: Polymer Chemistry 2011, 49, 4518.
33 Zhao, J.; Yuan, W. Z.; Xu, A.; Ai, F.; Lu, Y.; Zhang, Y. “Perfluorinated sulfonic acid ionomer/poly (N-vinylpyrrolidone) nanofiber membranes: Electrospinning fabrication, water stability, and metal ion removal applications” Reactive and Functional Polymers 2011, 71, 1102.
32 Luo, X.; Holdcroft, S.; Mani, A.; Zhang, Y.; Shi, Z. “Water, proton, and oxygen transport in high IEC, short side chain PFSA ionomer membranes: consequences of a frustrated network” Physical Chemistry Chemical Physics 2011, 13, 18055.
31 Xu, A.; Zhao, J.; Yuan, W. Z.; Li, H.; Zhang, H.; Wang, L.; Zhang, Y. “Tetrafluoroethylene Copolymers with Sulfonyl Fluoride Pendants: Syntheses in Supercritical Carbon Dioxide, Polymerization Behaviors, and Properties” Macromolecular Chemistry and Physics 2011, 212, 1497.
30 Qin, S.; Li, H.; Yuan, W.; Zhang, Y. “Hierarchical self-assembly of fluorine-containing diblock copolymer: From onion-like nanospheres to superstructured microspheres” Polymer 2011, 52, 1191.
29 Yuan, W. Z.; Chen, S.; Lam, J. W.; Deng, C.; Lu, P.; Sung, H. H.; Williams, I. D.; Kwok, H. S.; Zhang, Y.; Tang, B. Z. “Towards high efficiency solid emitters with aggregation-induced emission and electron-transport characteristics” Chemical Communications 2011, 47, 11216.
2010
28 Li, L.; Shang, F.; Wang, L.; Pei, S.; Zhang, Y. “Transport properties of PFSA membranes with various ion exchange capacities for direct methanol fuel cell application” Energy & Environmental Science 2010, 3, 114.
27 Wen, X. W.; Pei, S. P.; Li, H.; Ai, F.; Chen, H.; Li, K. Y.; Wang, Q.; Zhang, Y. M. “Study on an antifouling and blood compatible poly (ethylene–vinyl acetate) material with fluorinated surface structure” Journal of Materials Science 2010, 45, 2788.
26 Pei, S.; Qu, S.; Zhang, Y. “Direct Electrochemistry and Electrocatalysis of Hemoglobin at Mesoporous Carbon Modified Electrode” Sensors 2010, 10, 1279.
2009
25 Zhao, H.; Yang, J.; Li, L.; Li, H.; Wang, J.; Zhang, Y. “Effect of over-oxidation treatment of Pt–Co/polypyrrole-carbon nanotube catalysts on methanol oxidation” International Journal of Hydrogen Energy 2009, 34, 3908.
24 Su, L.; Li, L.; Li, H.; Zhang, Y.; Yu, W.; Zhou, C. “Perfluorosulfonic acid membranes treated by supercritical carbon dioxide method for direct methanol fuel cell application” Journal of Membrane Science 2009, 335, 118.
23 Li, W.; Li, H.; Zhang, Y. M. “Preparation and investigation of PVDF/PMMA/TiO2 composite film” Journal of Materials Science 2009, 44, 2977.
22 Su, L.; Li, L.; Li, H.; Tang, J.; Zhang, Y.; Yu, W.; Zhou, C. “Preparation of polysiloxane modified perfluorosulfonic acid composite membranes assisted by supercritical carbon dioxide for direct methanol fuel cell” Journal of Power Sources 2009, 194, 220.
21 Su, L.; Pei, S.; Li, L.; Li, H.; Zhang, Y.; Yu, W.; Zhou, C. “Preparation of polysiloxane/perfluorosulfonic acid nanocomposite membranes in supercritical carbon dioxide system for direct methanol fuel cell” International Journal of Hydrogen Energy 2009, 34, 6892.
20 Shang, F.; Li, L.; Zhang, Y.; Li, H. “PWA/silica/PFSA composite membrane for direct methanol fuel cells” Journal of Materials Science 2009, 44, 4383.
19 Chen, H.; Li, H.; Pei, S.; Wen, X.; Zhang, Y. “Synthesis and characterization of fluoropoly (amide–sulfonamide) s via polycondensation” Polymer 2009, 50, 4317.
18 Chen, H.; Huang, Z.; Li, H.; Zhang, Y.; Liu, Y. “Synthesis of pure (Co) polymers via supported cobalt (II)-catalyzed controlled/“living” radical polymerization” Polymer Bulletin 2009, 62, 151.
17 Han, L.; Zhang, Y.; Li, H.; Li, L. “The synthesis and surface activity of perfluoro-2, 5-dimethyl-3,6-dioxanonanoic acid ester fluorocarbon surfactants’’ Colloids and Surfaces A: Physicochemical and Engineering Aspects 2009, 334, 176.
2008
16 Luan, Y.; Zhang, Y.; Zhang, H.; Li, L.; Li, H.; Liu, Y. “Annealing effect of perfluorosulfonated ionomer membranes on proton conductivity and methanol permeability” Journal of Applied Polymer Science 2008, 107, 396.
15 Huang, Z. X.; Zhang, Y. M.; Li, H.; Liu, Y. G. “Controlled/“living” radical polymerization of methyl methacrylate catalyzed by cobalt acetate” Macromolecular Chemistry and Physics 2008, 209, 825.
14 Luan, Y.; Zhang, H.; Zhang, Y.; Li, L.; Li, H.; Liu, Y. “Study on structural evolution of perfluorosulfonic ionomer from concentrated DMF-based solution to membranes” Journal of Membrane Science 2008, 319, 91.
13 Huang, Z. X.; Zhang, Y. M.; Li, H.; Luan, Y. H.; Liu, Y. G. “Atom transfer radical polymerization of methyl methacrylate catalyzed by ion exchange resin immobilized Co (II) hybrid catalyst” Journal of Polymer Science Part A: Polymer Chemistry 2008, 46 , 1416.
12 Li, L.; Zhang, Y. “Chemical modification of Nafion membrane with 3,4-ethylenedioxythiophene for direct methanol fuel cell application” Journal of Power Sources 2008, 175, 256.
11 Zhao, H.; Li, L.; Yang, J.; Zhang, Y. “Co@ Pt–Ru core-shell nanoparticles supported on multiwalled carbon nanotube for methanol oxidation” Electrochemistry Communications 2008, 10, 1527.
10 Zhao, H.; Li, L.; Yang, J.; Zhang, Y. “Nanostructured polypyrrole/carbon composite as Pt catalyst support for fuel cell applications” Journal of Power Sources 2008, 184, 375.
9 Luan, Y.; Zhang, Y.; Li, L.; Zhang, H.; Zhang, Q.; Huang, Z.; Liu, Y. “Perfluorosulfonic ionomer solution in N, N-dimethylformamide” Journal of Applied Polymer Science 2008, 107, 2892.
8 Zhao, H.; Li, L.; Yang, J.; Zhang, Y.; Li, H. “Synthesis and characterization of bimetallic Pt–Fe/polypyrrole–carbon catalyst as DMFC anode catalyst” Electrochemistry Communications 2008, 10, 876.
2007
7 Huang, Z.; Zhang, Y.; Li, H.; Liu, Y. “A novel immobilized cobalt (II)/copper (II) bimetallic catalyst for atom transfer radical polymerization (ATRP) of methyl methacrylate” Applied Catalysis A: General 2007, 332, 192.
6 Li, L.; Zhang, Y.; Drillet, J. F.; Dittmeyer, R.; Jüttner, K.M. “Preparation and characterization of Pt direct deposition on polypyrrole modified Nafion composite membranes for direct methanol fuel cell applications” Chemical Engineering Journal 2007, 133, 113.
2006
5 Li, H.; Zhang, Y. M.; Zhang, H.; Xue, M. Z.; Liu, Y. G. “Novel, well-defined polystyrene with a fluorine cluster end-capped group: Synthesis, characterization, and surface properties” Journal of Polymer Science Part A: Polymer Chemistry 2006, 44, 3853.
4 Huang, Z.; Zhang, Y.; Zhao, C.; Qin, J.; Li, H.; Xue, M.; Liu, Y. “Direct gas-phase epoxidation of hexafluoropropylene with molecular oxygen using Ag catalyst” Applied Catalysis A: General 2006, 303, 18.
2005
3 Dou, H. Y.; Ni, H.-B.; Zhao, C.-X.; Zhang, Y. M. “EPR studies on H-abstraction from methylbenzenes by “magic blue” reagent” Journal of Fluorine Chemistry 2005, 126, 1130.
2 Li, Z. H.; Zhang, Y. M.; Xue, M. Z.; Zhou, L.; Liu, Y. G. “Atom transfer radical polymerization of methyl methacrylate catalyzed by cobalt catalyst system” Journal of Polymer Science Part A: Polymer Chemistry 2005, 43, 5207.
1 Li, Z.; Li, H.; Zhang, Y.; Xue, M.; Zhou, L.; Liu, Y. “A hybrid supported nickel catalyst for the controlled radical polymerization of methyl methacrylate” Applied Catalysis A: General 2005, 292, 61.
著作：
1 生物高分子第2卷類聚異戊二烯/[日] 古山種俊(Koyama, T.), [德] A. 斯泰陰比歇爾(Steinbüchel, A.) 主編; 劉燕剛，薛敏釗，張永明主譯. 北京：化學(xué)工業(yè)出版社(現(xiàn)代生物技術(shù)與醫(yī)藥科技出版中心) 2004, 8.
2 含氟功能材料. 張永明，李虹，張恒. 北京：化學(xué)工業(yè)出版社 2008.
3 PEM Fuel Cell Failure and Mode Analysis. Wang, H.; Li, H.; Yuan, X.-Z. Eds; Chapter 4, Luan, Y.; Zhang, Y. Membrane Degradation, Boca Raton: CRC Press, Taylor & Francis Group, 2011, December
Tel: 0086-21-34202613 Fax: 0086-21-54742567
E-mail : ymzhang@sjtu.edu.cn
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